Dialogue: The film won for Best Adapted Screenplay and the interactions between the two start off slow and in small sentences. But over time Anton begins to ask questions in bigger sentences in a mono-tone voice. The Proprietor begins to get confused as to why he's being asked so many questions and he soon realizes in his worried voice that there's more to Anton than him being just some average customer. 

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Questions: The questions go as follows (broadly); why's it your business? Will there be anything else? Is there something wrong? Wrong with what? What time do you close? You don't know what you're talking about, do you? What time do you go to bed? You live in that house out back? Live here your whole life? did you marry into this shop? And finally... What's the most you've ever lost in a coin toss?

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The Toss: The Coin Toss is what causes the suspense in this scene. Anton throws the coin up in the air, catches it, then puts it on the table. Anton asks for the Proprietor to call the coin. They didn't make a bet on anything. But based on the annoyance in Anton's voice, it seems to be that Anton hopes to kill this man if he gets it wrong. Proprietor... Without knowing... Bet everything in his life. 

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The Win: The Proprietor wins. The coin was heads up. 

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Cinematography: The film was shot by Roger Deakins (and he'd get nominated for his work on this film) and the scene only has 4 shots in the whole thing. One outside to set-up where they are, a shot on Anton, a shot on Proprietor and a shot on the coin on the table. You don't need any extravagant shots to set up and shoot a scene to add suspense to it. 

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Lighting: There is no light needed for this scene considering that the whole scene features a bright sun in the middle of the summer to show where the characters are... Nowhere in sight. 

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Music: Music can be heard for only a few seconds. When the Proprietor calls the coin and it's revealed he won. The music quickly fades out telling you that the intensity of the action has finally ended and Anton is ready to move on on his journey. 

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Directing: The Coen brothers do an excellent job at crafting a suspense scene that doesn't need guns, music, screaming and whatever is used in an action blockbuster. They use silence and small dialogue between two characters to set up the coin toss which can lead to either death or relief. 

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Acting: Gene Jones as the Gas Station Proprietor and Javier Bardem as Anton Chigurh have great chemistry with each other in this scene. What starts off as small talk from a worker to a customer turns into something more. 

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Conclusion: I believe this scene signifies that anything could happen to you anywhere. You could be mining your own business then he could be approached and asked questions about your life. Which could lead to a deadly ending. This doesn't happen in real life, though... But in fiction it does.